a) You are provided with solid L. Use it to carry out the tests below and record your results in the table provided.
TEST |
OBSERVATION |
INFERENCES |
a) Transfer all solid L into a boiling tube. Add 10cm3 of 1M HNO3 and shake Dip a glass rod into calcium Hydroxide solution and place it at the mouth of the boiling tube. |
1 mk |
½ mk |
b) To about 2 cm3 of the solution in a test tube add 3 drops of lead II Nitrate solution and warm |
1 mk |
½ mk |
c) To about 2 cm3 of the solution in another test tube add 2M sodium Hydroxide solution drop wise till in excess |
½ mk |
½ mk |
d) To about 2 cm3 of solution in another test tube dip a clean metallic spatula in the solution and place it on a burner flame. |
½ mk |
½ mk |
b) You are provided with solid Q, you are required to:
i) Carry out the tests described below on solid Q
ii) Record your observations and inference accordingly
iii) Test any gases provided.
Procedure:
i) Place a spatula full of solid Q in a boiling tube
ii) Add about 15 cm3 of distilled water and shake
iii) Divide the resulting solution into four portions
iv) Use a universal indicator paper to test portion one of the solution
Observation |
Inferences |
(1/2 mark) |
(1/2 mark) |
v) Add a spatula full of sodium carbonate to the second portion.
Observation |
Inferences |
(1/2 mark) |
(1/2 mark) |
vi) Add three drops of acidified Potassium Manganate (vii) solution to the third portion.
Observation |
Inferences |
(1/2 mark) |
(1/2 mark) |
You are provided with solid P. Carry out the tests below. Identify any gas (es) produced. Record your observations and inferences in the spaces provided.
(a) Place about half of the solid P in a dry test tube. Heat the solid gently.
Observation |
Inferences |
(1 mark) |
(1 mark) |
(b) Dissolve the remaining portion of solid P in 10cm3 of distilled water in a boiling tube. Divide the solution into four portions To the first portion, add sodium hydroxide dropwise till in excess.
Observation |
Inferences |
(1 mark) |
(1 mark) |
(c ) To the second portion, add 3 drops of ammonia solution followed by 1cm3 of hydrogen peroxide
Observation |
Inferences |
(1 mark) |
(1 mark) |
(d) To the third portion, add about 1cm3 of nitric acid solution
Observation |
Inferences |
(1 mark) |
(1 mark) |
(e) To the fourth portion, add 3 drops of barium nitrate solution.
Observation |
Inferences |
(1 mark) |
(1 mark) |
You are provided with solid Q. Carry out the test below. Write your observations and inferences in the spaces provided.
(a) Using a spatula place about one third of solid Q in a clean dry test-tube and heat it strongly.
Observation |
Inferences |
(1 mark) |
(1 mark) |
(b) Place the remaining solid Q in a boiling tube. Add about 10cm3 of distilled water. Shake the mixture thoroughly for about one minute. Filter and divide the filtrate into four portions.
Observation |
Inferences |
(1 mark) |
(1 mark) |
(c) To the first portion, add 2 drops of phenolphthalein indicator
Observation |
Inferences |
(1/2 mark) |
(1 mark) |
(d) To the second portion, add 2cm3 of dilute hydrochloric acid.
Observation |
Inferences |
(1/2 mark) |
(1 mark) |
(e) To the third portion, add 5cm3 of aqueous sodium sulphate
Observation |
Inferences |
(1 mark) |
(1 mark) |
(f) To the fourth portion, add dilute sodium hydroxide dropwise until in excess.
Observation |
Inferences |
(1 mark) |
(1 mark) |
You are provided with:-
- Solution A containing 4.0g sodium hydroxide per litre solution.
- Aqueous hydrochloric acid solution.
- Calcium hydroxide
– Solid C.
You are required to standardize hydrochloric acid solution B using solution A and hence determine the solubility of solid C in 100g of water at room temperature.
PROCEDURE I
- Place all the solid C into a clean conical flask.
- Measure accurately 100cm3 of distilled water using a measuring cylinder and add it to solid C.
- Shake thoroughly and leave it to stand for 12 minutes.
- Fill the burette with solution B.
- Pipette 25cm3 of solution A into a clean conical flask.
- Add 3 drops of phenolpthalein indicator and titrate with solution B.
- Record the results in the table below.
- Repeat the experiment to obtain three consistent readings
Experiment |
I |
II |
III |
Final burette reading (cm3) |
|
|
|
Initial burette reading (cm3) |
|
|
|
Volume of solution B used (cm3) |
|
|
|
(a) Determine the average volume of solution B used. (1 mark)
(b) Determine the molarity of solution A. ( 1 mark)
(c) Determine the molarity of solution B. (2 marks)
PROCEDURE II
-Filter the saturated solution of the mixture C and water into a clean conical flask and label this solution C.
-Using pipette and filler, transfer 25cm3 of the filtrate into a conical flask and titrate with hydrochloric acid solution B using methyl orange indicator.
-Record the results in the table below.
-Repeat the titration to obtain consistent readings
Experiment |
I |
II |
III |
Final burette reading (cm3) |
|
|
|
Initial burette reading (cm3) |
|
|
|
Volume of solution B used (cm3) |
|
|
|
(a) Determine the average volume of solution B used. ( 1 mark)
(b) Determine the number of moles of solution B used. ( 1mark)
(c ) Calculate the number of moles of C in 25cm3 of the filtrate. ( 2 marks )
(d) Calculate the number of moles of solid C in 100cm3 of solution . ( 1 mark)
(e) Calculate the solubility of solid C per 100g of water ( Ca = 40.0, O = 16.0, H = 1.0) Density of water = 1 g/cm3 (2 marks)
You are provided with the following apparatus.
Procedure:
a) Arrange the lit candle and the white screen on the bench at a distance of 100 cm from each other. Mount the metre rule on the bench as shown so that its zero mark coinside with the point of the lit candle and the 100 cm mark coinside with the point of the screen.
b) Place the lens between the screen and the lit candles at a point near the candle. Move the lens systems together with it holder towards the screen until you obtain a sharp magnified inverted image of the flame of the lit candle on the screen.
Record distance U1 between the lens and the lit candle.
U1 = ................................................................................................................................................cm ( ½ mk)
c) Move the lens system further towards the screen until you obtain another position where sharp diminished inverted image of the flame is formed on the screen.
Record the new distance u2 of the lens
u2 .............................................( ½ mk)
d) Determine displacement d of the lens system (1mk)
...........................................................................................................................................................
...........................................................................................................................................................
e) Determine the constant given that
and
(1mk)
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
You are provided with the following apparatus:
Procedure:
a) Set up the circuit shown below.
N/B: The arrows in the diagram indicate crocodile clips. The crocodile clip next to the cell should be used as a switch.Connect the crocodile clip next to the cell and disconnect the one at P.
Record the voltmeter reading V0.
V0 = ___________________________ (1mk)
b) Connect the crocodile clip at p, at a distance L = 50 cm from m.
Record the reading of both the ammeter and the voltmeter when the crocodile clip next to the cell is connected.
Reading of ammeter I = ........................................................................A ( ½ mk)
Reading of voltmeter V = ........................................................................V ( ½ mk)
c) Determine the quantity , given the following relationship. (3mks)
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
You are provided with the following apparatus
-Two metre rules
-One half metre rule
-Two pieces of cotton thread.
-Two heavy stands and two clamps
-One stop watch.
Procedure:
a) Set up the apparatus as shown in the figure below.
N/B:- Ensure the loops on the upper and lower metre rule are loose to enable easy sliding of the threads along the rules. Also the separation between the two rules must be 20cm throughout the experiment.
b) Adjust the position of the threads such that one is on the 10 cm mark and the other on the 90 cm. Mark on the lower metre rule. i.e d = 80 cm.
N/B: Maintain the threads vertical by making same adjustment on the upper metre rule.
Displace one end of the lower metre rule. Slightly on a horizontal plane so that when released it oscillated about a vertical axis as shown by the arrows In the figure. Measure the time for 20 Oscillations and record in the table below.
c) Repeat the procedure in (b) for other values of d shown in the table below (Set the values of d by adjusting the positions of the loops in steps of 5cm on both sides)
Complete the table
d (cm) |
80 |
70 |
60 |
50 |
40 |
30 |
d (m) |
|
|
|
|
|
|
1/d2 ( m-2) |
|
|
|
|
|
|
Time for 20 Osc. (s) |
|
|
|
|
|
|
Period T (s) |
|
|
|
|
|
|
T2 (s2) |
|
|
|
|
|
|
(10mks)
d) Plot a graph of T2( y – axis) against 1/d2. (5mks)
e) i) Determine the slope of your graph. (3mks)
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
ii) Given that where K is a constant; determine the value of k. (2mks)
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
You are provided with the following apparatus:
Procedure:
(a) Pour exactly 20cm3 of water into the measuring cylinder
(b) Tie one end of the thread provided to the hooked mass using the thread lower the 50g mass carefully and gently into the water contained in the measuring cylinder. Record the new level V1 of water in the measuring cylinder.
V1 = _________________________________cm3 (1mk)
(c) Detouch the thread from the mass at a point near the hook. Wind five close turns round the mass. Place an ink mark at the beginning of the first turn and at the end of the fifth turn. Unwind the thread and determine length L between the two ink marks using the half metre rule.
L = _________________________________mm (1mk)
(d) Determine the quantity K defined by: (1mk)
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
e) Find the quantity Q defined by: 2mks
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
You are provided with the following apparatus:
Procedure:
(a) Using the office pins provided mount one sheet of plain paper on the soft board. Place the rectangular glass block on the plain paper and trace around it using a pencil.
(b) Remove the block, draw a normal at a point O and draw a line making an angle of 150 with the normal to represent incident ray as shown in the diagram below.
(c) Stick two optical pins P and Q along the incident ray and replace the glass block. While closing one eye, look through the glass block from the opposite side and insert two other pins R and S exactly in line with the images of P and Q.
(d) Remove the glass block and join SR to the outline of block. Hence obtain the refracted ray inside the glass block as shown in the diagram.
(e) With O as the centre, Draw a circle of radius 5 cm to cut both the incident ray and the refracted ray at M and L respectively.
f)Using a set square, draw the perpendiculars LY and MN. Measure LY and MN in millimeters and record your value in the table below.
Angle of incidendence i |
15 |
3 |
45 |
60 |
75 |
LY (mm) |
|
|
|
|
|
MN (mm) |
|
|
|
|
|
g) Repeat the above steps for other angles of incidence shown in the table above.
h) Plot a graph of LY ( y – axis) against MN. (5mks)
(i) Calculate the slope,, of your graph. (2mks)
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
j) Determine the quantity defined by
= Sin -1
(2mks)
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
N/B: Plain papers containing your drawing should be submitted together with the question paper to the invigilator.
You are provided with the following;
Proceed as follows;
(a) Set up the apparatus as shown below.
(b) Heat the water in the beaker provided and leave it to boil
(c) Wrap the given piece of duplicating paper round the bulb of the thermometer. Use rubber band to hold the paper in place.
(d) Place the thermometer inside in the dry test tube.
(e) Place the test tube in the water as shown in the diagram above. Make sure that the water does not enter the test tube. Leave the test tube in the boiling water until the thermometer indicates a steady temperature.
(f) Remove the thermometer and immediately start the stop watch.
(g) While holding the thermometer in air record the readings of the thermometer T1 at intervals of 30seconds for 10 minutes.
Time in minutes |
0 |
0.5 |
1.0 |
1.5 |
2.0 |
2.5 |
3.0 |
3.5 |
4.0 |
4.5 |
5.0 |
5.5 |
T1 (0c) |
|
|
|
|
|
|
|
|
|
|
|
|
T2(0c) |
|
|
|
|
|
|
|
|
|
|
|
|
Time in Minutes |
6.0 |
6.5 |
7.0 |
|
8.0 |
8.5 |
9.0 |
9.5 |
10.0 |
T1 (oC) |
|
|
|
|
|
|
|
|
|
T2 (oC) |
|
|
|
|
|
|
|
|
|
(10mrks)
(h) Place the wrapped thermometer directly into boiling water. Leave the thermometer in the boiling water until it indicates a steady temperature.
(i) Repeat procedure (f) and (g) and record the reading T2 of the thermometer in the table at half minute intervals for 5minutes.
(j) Using the same axes on the grid provided, plot a graph of temperature (y-axis) against time for result obtained in (g) and (i) (label the graph T1 and T2)
(k) (8mrks)
(i) From the graphs determine;
I) For each graph the time for temperature to fall from 600C to 400C. (1mrk)
.........................................................................................................................................
.........................................................................................................................................
II) Find the ratio of the two times in k (i) above (1mrk)
.........................................................................................................................................
.........................................................................................................................................