All Questions

The apparatus below was used for the preparation of iron (III) chloride in the laboratory. Study it and use it to answer the questions that follow.

 


                                          

a) Why is it preferred to use calcium oxide rather than calcium chloride in the guard tube? (2 Marks)

 

 

b) What property of iron (III) chloride makes it possible to be collected as shown in the diagram? (1 Mark)

Magnesium reacts by losing its 2 valence electrons. How does its 1st and 2nd ionization energy compare? Explain (2 Marks)

A luminous flame produces bright yellow light. Explain (1 Mark)

The following apparatus was set up to investigate the percentage of oxygen in air by slowly passing 100cm3 of air from syringe A to syringe B and then back until the volume of air remained constant. Study it and use it to answer the questions that follow.


                                   

a) Identify the mistake in the setup (1 Mark)

 

 

b) Why was the air moved slowly from syringe A to syringe B and vice versa? (1 Mark)

 

 

c) Write an equation for the reaction that took place in the combustion tube after the mistake was corrected (1 Mark)

Calculate the number of sulphate ions in 150cm3 of 0.1M aluminium sulphate, Al2(SO4)3 (3 Marks)   (L = 6.023 × 1023)

20cm3 of a solution containing 2.7g/dm3 of an alkali XOH completely reacted with 25cm3 of 0.045M sulphuric (VI) acid. Calculate the relative atomic mass of element X (O = 16, H = 1) (3 Marks)

The electron arrangement of ions W3+ and Z2- are 2.8 and 2.8.8 respectively.

a) In which groups do elements W and Z belong?   (1 Mark)

 

 

b) Write the formula of the compound that would be formed between W and Z   (1 Mark)

Calculate the volume of oxygen produced when 10g of silver nitrate was completely decomposed by heating at standard temperature and pressure
(Ag = 108, N = 14, O = 16, Molar gas volume at s.t.p. = 22400cm3) (3 Marks)

400cm3 of a gas D diffuses through a porous plug in 50 seconds, while 600cm3 of oxygen gas diffuses from the same apparatus in 30 seconds. Calculate the relative molecular mass of gas D. (O = 16) (2 Marks)

The information in the table below relates to the physical properties of the chlorides of certain elements.

Formula of compound

NaCl

MgCl2

AlCl3

SiCl4

PCl3

SCl2

Boiling point (0C)

1470

1420

Sublimes at  1800C

60

75

60

Melting point (0C)

800

710

 

-70

-90

-80

a) Select two chlorides that are liquid at room temperature (2 Marks)

 

 

b) Explain why AlCl3 has a much lower melting point than MgCl2, although both aluminium and magnesium are metals. (2 Marks)